So this is an ASP application who makes use of a 32 bit dll and connects to MS SQL.
You'd better tell when did the error happen. Did it happen only if the page tried to access MS SQL? Or a very simple ASP page who doesn't use MS SQL experienced the same issue.
Also you can check if MS SQL native client is installed properly,
http://msdn.microsoft.com/en-us/library/ms131334%28SQL.90%29.aspx
If you are not sure how to check that, you can post to our SQL Server forums,
http://social.msdn.microsoft.com/Forums/en-US/category/sqlserver/