It is just that simple. Unless you have to change configurations for anything to run in 64 bit. :)
A better option is often to pull machines from the cluster, upgrade them, join them in their new cluster, swap the clusters and reconfigure the other machines for the new cluster. But that's not exactly required. And most of what you'll encounter isn't related to IIS.
Backup everything, try it with one, see what breaks.
Jeff
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