Hi,
If the request ends up creating a new IIS worker process which will in turn create a new PHP proces, start time and initialization time is definitely going to add up. New appwarmup extension which can be used with IIS 7.5 can help with this by executing set of URLs before apppool is reported as started. Just out of curiosity, which application are you running? How much time the first request is taking?
Thanks,
Kanwal