Are you talking about memory paging or are you talking about performance of an web page?
Memory Paging: If you have an application that is memory intensive resulting in heavy paging then yes you will see benefits of moving onto 64bit as your application will have pretty much infinite virtual memory to use and thus will not result in paging. Ofcourse all this is assuming that you will also have enough physical memory on the machine.
Web page: It is difficult to answer without knowing what the page is doing. But if this is a simple .aspx page, which doesn't require lot of memory, than it will perform better on Wow64 than when run on native x64. Typically when run under Wow64 applications have a smaller memory footprint and they tend to be slightly faster.
Overall it is prudent to port your 32-bit applications to 64-bit.
Thanks,
Mukhtar Desai
IIS Performance Team